Effect of Additives on the flexibility of High-Density Polyethylene Filled Cowhide Composite

Authors

DOI:

https://doi.org/10.56919/usci.1122.014

Keywords:

Composite Flexibility, Mechanical strength, HDPE, Plant treated hide, Untreated cowhide waste

Abstract

Fibre-filled high-density polyethylene composite was prepared by two roll melt mixing, and pressed into standard shapes using compression moulding technique for varying fibre contents from 10% by weight up to 60w% by weight. Tests were performed on composite specimens in accordance with ASTM D638. Additives have been incorporated into the design formulation of the composite to provide flexibility and intercalate (adhesion) between the fibre and the substrate. The results obtained were compared with specimens made of 100% weight of high-density polyethylene (HDPE). Results showed that waste loads in the range of 10-40% weight for un-treated hides (UH) and plant treated cowhide (acacia nilotical) (VT), represent good mechanical, physical, thermal and morphological properties, with improved intercalation between the fibre and interface substrate due to additives. 10-40 % weight (non-degradable) HDPE can be partially replaced with rawhide and processed shredded hide (both compostable), with the highest value at 10% by weight fibre content. The breaking strength of high-density polyethylene filled untreated hide with additive (HDPE/UHA) and high-density polyethylene filled plant treated hide with additives (HDPE/VTA) stretches longer under tension by 32.7% and 3.9% respectively, more than the control at 40% content by weight. The composites are suitable for producing composite-films, useful for manufacturing bags for packaging food goods, or in shoe soles, floor tiles and any material property requiring flexibility.

References

Ali, Y., Bahri, B. and Aykut, S. (2020). Value Addition to Leather Industry Wastes and By-Products: Hydrolyzed Collagen and Collagen Peptides. In: Book Citation Index in Web of Science Core Collection. https://doi.org/10.5772/intechopen.92699

Ambrósio, J. D., Alessandra, A. L., Baltus, C. B. and Sílvia, H. P. B. (2011). Natural Fiber Polymer Composites Technology Applied to the Recovery and Protection of Tropical Forests Allied to the Recycling of Industrial and Urban Residues In: T. Pavla (Ed.) Advances in Composite Materials – Analysis of Natural and Man-Made Materials, ISBN: 978-953-307-449-8, Retrieved 24th April, 2015.

Asep, B., Rasi, O. and Risti, R. (2019) How to Read and Interpret FTIR Spectroscope of Organic Material Indonesian Journal of Science and Technology: 4 (1): 97-118. https://doi.org/10.17509/ijost.v4i1.15806

Benzler, B., (2013), Mettler Toledo: Thermal Analysis of Polymers Application Handbook, Giessen Germany, p1-18.

Charles, M. (2022). Plastic Pollution, Definition, Source, Effects, Solutions and Facts. In Plastic Pollution. Encyclopaedia Britannica Retrieved on 18th October, 2022 from https://www.britannica.com.

Chrońska, K. and Przepiórkowska, A. (2011), A mixture of buffing dust and chrome shavings as a filler for nitrile rubbers, International Journal of Polymer Science Part A: 122(5): 2899–2906. https://doi.org/10.1002/app.33629

Clare, A. (2021).Waste Reduction the Leather Industry 33- Reusing Leather Solid Wastes; A Circular Economy Model. Retrieve 12th June, 2022 from https://www.authenticae.co.uk

Elena, B., Cristina, C., Emanuel H., Claudu S. and Maria-Cristina, L. (2019), The effect of Halloysite NanoTubes Dispersions on Vegetable-Tanned Leather, Thermal Stability, Heritage Science, 7(68): 1- 14. https://doi.org/10.1186/s40494-019-0310-x

España, J.M., Samper, M.D., Fages, E., Sánchez-Nácher L. and Balart R. (2013). Investigation of the effect of different silane coupling agents on mechanical performance of basalt fiber composite laminates with biobased epoxy matrices; Society of Plastics Engineers,34(3): 376–381. https://doi.org/10.3390/polym13010117

Eze,, U. W., Ishidi, E. Y.; Uche, C. A and Ohanuzue, C. B. C. (2016). Effect of Compatibilizing Agent on Mechanical Properties of Waste Paper and Gracinia kola Filled Low Density Polyethylene Composites, International Journal of Innovative Scientific and Engineering Technologies Research 4(1):24-30.https://www.researchgate.net/publication/339956658

Hang, L.T., Viet, D.Q., Linh, N.D.P., Dang,H.-L.T., Dao, V.-D. And Tuan, P.A., (2021). Utilization of Leather Waste Fibres in Polymer Matrix Composites Based on Acrylonitrile-Butadiene Rubber: Polymers 2021, 13, 117. https://doi.org/10.3390/polym13010117

Ibe, K. E., Uche, I., Gabriel, O.T., Mark, D.A. and Mosunmade, O.A. (2020), Natural Fibre Reinforced Polymer Composite (NFRPC) from waste Polypropylene Filled with Coconut Flour. International Journal of Engineering Technology and Sciences. 6. (2): 50-64. https://doi.org/10.15282/ijets.v6i2.2882

Jefri, B., Kristomus, B. and Marselinus, N., (2017), Natural Composite Reinforced by Loontar (borassus flabellifer) Fiber: An Experimental Study on Open-Hole Tensile Strength. International Journal of Biomaterials. https://doi.org/10.1155/2017/7685047

Jerzy, J. C. and Elżbieta, L. (2012), Modification of Thermoplastics with Reactive Silanes and Siloxanes, Thermoplastic Elastomers, Adel El-Sonbati (Ed.), ISBN: 978-953-51-0346-2, In: Tech, Available from: http://www.intechopen.com/books/thermoplastic elastomers/modification-of-thermoplastics-with-reactive silanes-and-siloxanes.

Jinchun, Z., Huijun, Z., James, N. and Hrushikesh, A. (2013), Recent Development of Flax Fibres and Their Reinforced Composites Based on Different Polymeric Matrices; materials, Vol.6, 5171-5198. https://doi.org/10.3390/ma6115171

John, T. L. and Richard, F. G., (2005), Polymer Modifiers and Additives, Marcel Dekker, Inc. New York USA pp1-8.

Kilic, E., Oliver-Ortega, H.; Tarres, Q.; Delgado-Aguilar, M., Fullana-i-Paalmer, P. and Puig, R.; (2021). Valorization Strategy for Leather Waste as Filler for High-Density Polyethylene Composites: Analysis of the thermal Stability, Insulation Properties and Chromium Leaching. Polymer 2021, 13, 3313. https://doi.org/10.3390/polym13193313

Mohammad, R., Fatemeh, J., Abdulrasoul, O. and Amir, E. L. (2006), Mechanical Properties and Water Absorption Behaviour of Chopped Rice Husk Filled Polypropylene Composites, Iranian Polymer Journal, 15(9): 757-766.

Mohit, S., Dharmpal, D. and Guptac,V.K (2015), Effect of Fiber Chemical Treatment on Mechanical Properties of Sisal Fiber/Recycled HDPE Composite, Materials Today: Proceedings 2: 3149 – 3155. https://doi.org/10.1016/j.matpr.2015.07.103

Mohanty, K. A., Misra, M. and Drzal, T. L. (2005), Natural Fibers Biocomposites, Taylor and Francis (CRC), London, pp125-129.

Murali, S., Balaraman, M. and Jonnalagadda, R. R., (2019). Leather Solid Waste: An Eco-benign Raw Material for Chemical Preparation- A Circular Economy Example. Waste Management. 87: 357-367. https://doi.org/10.1016/j.wasman.2019.02.026

Musa, E.T., Ahmed, A.S., Ishiuku, U.S., Abba, H., Yerima, Y. and Kolawole, E.G. (2019), Effect of UV-Light on the Mechanical and Morphological Properties of Waste Cow Leather-HDPE Composite, Jewel Journal of Scientific Research,4(1&2): 10-18 ISSN: 2384-6267

Musa, E.T., Hamza, A., Ahmed, A.S. and Ishiuku, U.S. (2016), Effect of Vegetable (Acacia nilotica) Tanned Waste on the Mechanical and Physical Properties of High-Density Polyethylene, Nigerian Journal of Scientific Research, 15(2): 176-181

Musa, E.T., Hamza, A., Ahmed, A.S., Ishiuku, U.S. and Yerima, Y., (2022), Mechanical and Physical Properties of High-Density Polyethylene (HDPE)/Cow Waste Leather Composite, International Journal of Current Research and Applied Studies, 1(3): 10-27. https://ijcras.com .

Nahar, S.; Khan, R. A.; Dey, K.; Sarker, B.; Das, A. K. and Ghoshal, S. (2014), Comparative studies of mechanical and interfacial properties between jute and bamboo fiber-reinforced polypropylene-based composites. Journal of Thermoplastic Composite Materials, 25 (1):15-20. https://doi.org/10.1177/0892705711404725

Priebe, G.P.S. and Gutterres, (2017).Special Review: Anaerobic Digestion of Leather Industry Waste- an Alternative Source of Energy. Journal-American Leather Chemist Association 112(2): 59-71 retrieved on 17th October, 2022 from https://jornals.uc.edu

Parisi, M.; Nanni, A. and Colonna, M., (2021). Recycling of Chrome-Tanned Leather and its Utilization as Polymer Materials and in Polymer Bases Composites: A Review, Polymer 2021, 13,429. https://doi.org/10.3390/polym13030429

Pickering, K. L., AruanEfendy, M. G. and Le, T. M. (2016), A review of recent developments in natural fiber Composites and their mechanical performance, Composites Part A, 83: 98-112. https://doi.org/10.1016/j.compositesa.2015.08.038

Rajendran, M., Manjusri, M., Fantahun, D. and Amar, K. M. (2016), Influence of processing parameters on the impact strength of biocomposites: A statistical approach, Composites: Part A 83: 120-129. https://doi.org/10.1016/j.compositesa.2015.09.003

Ramani, K., Venkatesan, S., Uddin, M. and Ganesan, S. (2020) Anaerobic Biovalorization of Solid Waste and Production of High Value-added Biomolecules and Biofuels. In: Biovalorisation of Wastes to Renewable Chemicals and Biofuels. Pp. 3-25 Elsevier Inc. https://doi.org/10.1016/B978-0-12-817951-2.00001-8

Todd, J. (2015). Composites and Plastics, Retrieved on 18th March, 2015 from http://compositesuk.co.uk/composite-materials

William, D.C. Jr., (2007), Material Science and Engineering, John Willey & Sons Inc. New York. Pp. 577- 607

Zanaib, Y.S. (2012) Mechanical And Physical Properties of High Density Polyethylene Filled With Carbon Black And Titanium Dioxide, Diyala Journal of Engineering Science, 05(01): 147-159. https://doi.org/10.24237/djes.2012.05112

Zlin, L. (2020). Leather and Leather Product Industry. United Nation Industrial Development Organization-UNIDO retrieved on 8th October, 2022 from https://www.unido.org

Downloads

Published

2022-09-30

How to Cite

Musa, Esther Turu, Hamza, Abba, Ahmed, Abdulkarim Salawu, Ishiaku, Umaru Semo, & Yerima, Yakubu. (2022). Effect of Additives on the flexibility of High-Density Polyethylene Filled Cowhide Composite. UMYU Scientifica, 1(1), 103–113. https://doi.org/10.56919/usci.1122.014