Characterization of the Structural and Optical Properties of Copper Oxide for Use in Solar Cells Using Screen Printing Method

Authors

DOI:

https://doi.org/10.56919/usci.1122.024

Keywords:

Copper oxide, temperature, Absorption, annealing, Screen printing, Morphology

Abstract

Structural and optical properties of copper oxide for solar cells applications was studied using screen printing techniques. Annealing procedure was employed in order to test the temperature effect. Samples were annealed at 150 oC and 200 oC for 30 minutes, the last sample was allowed to dry at room temperature. Scanning Electron Microscopy (SEM), UV-visible spectroscopy, and Fourier transforms infrared spectroscopy were used to describe the materials (FTIR). The results demonstrate that the annealing temperature had a substantial impact on the sample's structural properties. SEM analysis shows that the 150 oC annealed CuO sample have good morphology, no brittleness or cracking, and no gaps between crystal grains. The UV-visible spectrometer machine type Cary 50bio (0906m12) was used to analyze the absorption and percentage transmittance of the samples at room temperature, dry CuO sample and sample annealed at 150 oC have the strongest absorption in the visible band. The entire samples have a good transmittance for solar applications according to FTIR results. CuO sample annealed at 150 oC has a band gap 1.29eV which makes it good material for solar applications.

Author Biographies

Umar Abdullahi Bello, Department of Physics, Kebbi State University of Science and Technology Aliero

Dr. Abdullahi Bello Umar

DEPT. OF PHYSICS, KEBBI STATE UNIVERSITY OF SCIENCE AND TECHNOLOGY ALIERO

Mamuda Salihu, Department of science education, Kebbi State University of Science and Technology Aliero

Mamuda S.

Examination officer, DEPT. OF SCIENCE EDUCATION, KEBBI STATE UNIV. OF SCIENCE AND TECHNOLOGY ALIERO.

Abubakar Musa Ahmad, Department of Information and Communication Technology, Kebbi State University of Science and Technology Aliero

Ahmad A. M.

SIWES Cordinator, DEPT. OF INFOMATION and COMM. TECH., KEBBI STATE UNIV. OF SCIENCE AND TECHNOLOGY ALIERO

References

AL-Hasan N. H., (2010); Study of Annealing, Hardening and Tempering on Hardness and Microstructure of Mn-Fe Alloy, Journal of Basrah Researches ((Sciences)) Vol. 36, No. 3, 15 June (2010), ISSN 1817ــ2695

Alzaid M., Sajjad M., Ali K., Jamil Y., Akbar L., Sattar A., Rizwan A., Suhale A., Ahmad H., Nouman C. M., Ghani M. U., Umair A., (), Enhanced structural and optical properties of copper oxide for solar cell applications, Journal of Ovonic Research Vol. 16, No. 6, November - December 2020, p. 405 - 412. https://doi.org/10.15251/JOR.2020.166.405

Amar, H. J. (2014). Optical Properties,Structure,and Morphology of CuO Grown by Thermal Oxidation of Cu thin film on Glass Substrate, Journal of Kufa - Physics Vol.6/ No.1. Asha, A. R., Beena B. B., (2014). Structural and Optical Absorption Analysis of CuO Nanoparticles, Nanoscience Research Lab, Department of Chemistry, University of Kerala, Kollam, Kerala, India, pin-690521. Indian Journal of Advances in Chemical Science 2 Vol. 2, Pp. 158-161. Balıka M., Bulut V., Erdogan I. Y., (2018). Optical, structural and phase transition properties of Cu2O, CuO and Cu2O/CuO: Their photo electrochemical sensor applications, international journal of hydrogen energy xxx (2018) 1-12. [Crossref] https://doi.org/10.1016/j.ijhydene.2018.08.159

Berthomieu C., Hienerwadel R., (2009)

Review Fourier transform infrared (FTIR) spectroscopy, Photosynth Res (2009) 101:157-170. [Crossref] https://doi.org/10.1007/s11120-009-9439-x

Bhamu K. C., Amit Soni, Jagrati Sahariya (2018), Revealing optoelectronic and transport properties of potential perovskites Cs2PdX6(X = Cl, Br): A probe from density functional theory (DFT), Solar Energy 162 (2018) 336-343. [Crossref]

https://doi.org/10.1016/j.solener.2018.01.059

Bushra, K. H. Al-Maiyaly, I. H., Ayser, J. I. (2014). Effect Ambient Oxidation On structural And Optical Properties Of Copper Oxide Thin films International Journal Of Innovative Research in Science, Engineering and Technology, Vol. 3. [Crossref]

Butt, M. A. (2022); Thin-Film Coating Methods: A Successful Marriage of High-Quality and Cost-Effectiveness-A Brief Exploration. Coatings 2022, 12, 1115. [Crossref] https://doi.org/10.3390/coatings12081115

Daoudi O., Qachaou Y., Raidou A., Nouneh K., Lharch M., Fahoume M., (2018)

Study of the physical properties of CuO thin films grown by modified SILAR method for solar cells applications, Superlattices and Microstructures(2018). [Crossref]

Elam J. W., George S. M., (2003); Growth of ZnO/Al2O3Alloy Films Using Atomic Layer Deposition Techniques, Chem. Mater.2003,15,1020-1028. American Chemical Society. [Crossref] https://doi.org/10.1021/cm020607+

Fasasi A. Y., Osagie E., Pelemo D., Obiajunwa E., Ajenifuja A, Ajao J., Osinkolu G., Makinde W. O., Adeoye A. E.. (2018)

Effect of Precursor Solvents on the Optical Properties of Copper Oxide Thin Films Deposited Using Spray Pyrolysis for Optoelectronic Applications. American Journal of Materials Synthesis and Processing. Vol. 3, No. 2, 2018, pp. 12-22. [Crossref] https://doi.org/10.11648/j.ajmsp.20180302.12

Halder S., M. Sheikh, R. Maity, B. Ghosh, T.P. Sinha, Investigating the optical, photosensitivity and photocatalytic properties of double perovskites A2LuTaO6 (A = Ba, Sr): A combined experimental and density functional theory study, Ceramics International (2019). [Crossref]

https://doi.org/10.1016/j.ceramint.2019.05.053

Harish, K., Renu, R., (2013). Structural and Optical Characterization of ZnO Nanoparticles Synthesized by Microemulsion Route, International Letters of Chemistry, Physics and Astronomy, vol. 14.Pp. 26-36. [Crossref]

https://doi.org/10.18052/www.scipress.com/ILCPA.19.26

He Qiu, Bin Yu, Zhaohuai Li, and Yan Zhao. (2019). Review on Density Functional Theory for Battery Materials. Energy Environ. Mater. 2019, 0,1-16. Zhengzhou University. [Crossref]

Jayan K. Deepthi, and Varkey Sebastian, A review on computational modelling of individual device components and interfaces of perovskite solar cells using DFT, AIP Conference Proceedings 2162, 020036 (2019). [Crossref]

https://doi.org/10.1063/1.5130246

Khan S. A, Khan S. B., Khan L. U., Farooq A., Akhtar K., Asiri A. M. (2022);

Chapter 9 Fourier Transform InfraredSpectroscopy: Fundamentalsand Application in Functional Groupsand Nanomaterials Characterization, AvSpringer International Publishing AG, part of Springer Nature 2018S. K. Sharma (ed.), Handbook of Materials Characterization. [Crossref]

Khodair Z. T., Al-Jubbori M. A., Shano A. M,. Sharrad F. I, (2020)., Study of Optical and Structural Properties of (NiO)1-x (CuO)x Nanostructures Thin Films, Chemical Data Collections (2020). [Crossref]

https://doi.org/10.1016/j.cdc.2020.100414

Labroo P., Irvin J., Johnson J., Sieverts M., Miess J., Robinson I., Baetz N., Garrett C., Sopko N., (2020)

Physical characterization of swine and human skin: Correlations between Raman spectroscopy, Tensile testing, Atomic force microscopy (AFM), Scanning electron microscopy (SEM), and Multiphoton microscopy (MPM), Skin Res Technol. 2020;00:1-10., Published by John Wiley & Sons Ltd. [Crossref]

Mohammed A., Abdullah A., (2018)

Scanning Electron Microscopy (SEM): A Review, Proceedings of 2018 International Conference on Hydraulics and Pneumatics - HERVEX, November 7-9, Băile Govora, Romania, ISSN 1454 - 8003.

Mohd, R. J., Mohd, S. M., Suan, N. L., Hee, A. C. (2009). Annealing Effects on the Properties of Copper Oxide Thin Films Prepared by Chemical Deposition. Int. J. Electrochem. Sci., Vol. 6, Pp. 6094 - 6104.

https://doi.org/10.1016/S1452-3981(23)19665-9

Nandiyanto A. B. D, Oktiani R., Ragadhita R., (2019); How to Read and Interpret FTIR Spectroscope of Organic Material. Jounal of Science & Technology,Volume 4 Issue 1, April 2019. [Crossref] https://doi.org/10.17509/ijost.v4i1.15806

Oluyamo, S. S., Nyagba, M .S., Ojo, Ambrose. S., (2014). Optical Properties of Copper (I) Oxide Thin Films Synthesized BySilar Technique Iosr. Journal Of Applied Physics (Iosr-Jap) E-Issn: 2278-4861.Volume 6, Pp 102-105. [Crossref]

https://doi.org/10.9790/4861-0631102105

Prasanth D., Sibin K. P., Barshilia H. C., (2019); Optical properties of sputter deposited nanocrystalline CuO thin films, Thin Solid Films, [Crossref] https://doi.org/10.1016/j.tsf.2019.01.037

Roy, S. S., Bhuiyan, A. H., Podder, J. (2015). Optical and Electrical Properties of Copper Oxide Thin Films Synthesized by Spray Pyrolysis Technique, Sensors & Transducers, Journal of Nanoscience and Nanotechnology,Vol. 191, Issue 8, August, pp. 21-27.

Samir, H. A., Riyam, I. J., (2013). Study The Optical Properties Of Copper Oxide Thin Film Deposited By Cold Spray. Al - Qadisiya Journal For Engineering Sciences Vol. 6,,No.4.

Sandeep, S., and Dhananjaya, K. (2012). Effect of Annealing Temperature on the Structural and Optical Properties of Zinc Oxide (ZnO) Thin Films Prepared by Spin Coating Process Department of Sciences, Manipal University, Manipal-576 104, Karnataka, INDIA. International Conference on Materials Science and Technology (ICMST 2012).

Sultana J., Paul S., Karmakar A., Dalapati G. K., Chattopadhyay S., Optimizing the thermal annealing temperature: technological route for tuning the photo-detecting property of p-CuO thin films grown by chemical bath deposition method Journal of Materials Science: Materials in Electronics. [Crossref]

Tom J. (2022); Article on UV-Vis Spectroscopy: Principle, Strengths and Limitations and Applications Published by Technology networks analysis sepeartion, June 30, 2021 https://www.technologynetworks.com/

Yahaya A. A., Darma T. H. (2022); Investigation of optical and structural properties of zinc (ii) oxide using screen printing techniques for use in solar cells, International Research Journal of Modernization in Engineering Technology and Science, Volume:04/Issue:07/July-2022, e-ISSN: 2582-5208.

Downloads

Published

2022-09-30

How to Cite

Yahaya Abubakar Aliero, Abdullahi Bello, U., Salihu, M., & Ahmad, A. M. (2022). Characterization of the Structural and Optical Properties of Copper Oxide for Use in Solar Cells Using Screen Printing Method. UMYU Scientifica, 1(1), 184–193. https://doi.org/10.56919/usci.1122.024