Adsorption and inhibitive effect of N-[(4{[(Z)-(4-hydroxy phenyl) methylidene] amino} phenyl) sulfonyl acetamide on the corrosion of mild steel in HCl medium

Main Article Content

Chikezie Ogueji
Okoche K. Amadi
Divine C. Oranuka
Chineye A. Onwuka

Abstract

In this study, the inhibitive effects of Schiff’s base, N-[(4{[(Z)-(4-hydroxy phenyl) methylidene] amino} phenyl) sulfonyl acetamide (4-HPMAPSA) on mild steel corrosion in 1.0 M HCl(aq) at different temperatures were investigated using weight loss and scanning electron microscope.  The Fourier transform infrared spectrum and X-ray diffraction pattern of 4-HPMAPSA were obtained.  It was found that the inhibition effectiveness of 4-HPMAPSA relies on the temperature, 4-HPMAPSA concentration and exposure period.  4-HPMAPSA hinders mild steel corrosion and exhibits a maximum inhibitive efficiency of 88.5 % at 0.5 g of 4-HPMAPSA at 303 K.  The activation energy (Ea) value (45.0 to 52.3 kJmol-1) with an average of 47.7 kJmol-1 was obtained for the 4-HPMAPSA-inhibited reaction and 35.1 kJmol-1 for the uninhibited.  The thermodynamic values calculated for the 4-HPMAPSA-inhibited reaction show that the process is spontaneous and endothermic.  With an R2 value of 0.9646 to 0.9999, Langmuir isotherm best described the 4-HPMAPSA uptake behaviour.

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How to Cite
Ogueji, C., Amadi, O. K., Oranuka, D. C., & Onwuka, C. A. (2023). Adsorption and inhibitive effect of N-[(4{[(Z)-(4-hydroxy phenyl) methylidene] amino} phenyl) sulfonyl acetamide on the corrosion of mild steel in HCl medium. UMYU Scientifica, 2(4), 179–188. https://doi.org/10.56919/usci.2324.022
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