Corrosion Inhibition and Adsorption Behaviour of Centrosema pubescens Leaf Extract for Copper in HCl Solution
DOI:
https://doi.org/10.56919/usci.2434.018Keywords:
Inhibitor, Weight loss, Copper, Adsorption isothermAbstract
Study’s Excerpt
- In this study, Centrosema pubescens leaf extract (CPE) has been confirmed as eco-friendly and efficient green inhibitor for copper corrosion in hydrochloric acid.
- Detailed thermodynamic analysis, revealed that CPE adsorption follows a Freundlich isotherm model.
- SEM-EDX and FTIR characterizations confirmed the formation of a protective layer confirming the potentials of the plant extracts in sustainable corrosion prevention.
Full Abstract
The anti-corrosion behaviour of Centrosema pubescens leaf extract (CPE) on copper in 1.5 M hydrochloric acid was investigated using weight loss method at different temperatures, followed with scanning electron microscopy (SEM) surface characterization connected with energy dispersive X-ray spectroscopy (EDX). The Fourier transform infrared spectrum of CPE was obtained. CPE inhibition effectiveness depends on the temperature and its concentration. CPE restrains the copper corrosion with 94.26 % inhibition efficiency at 1.0 g/L of CPE and at 303 K. For the CPE-inhibited system, a higher activation energy (Ea) value (range of 31.09 to 38.70 kJmol-1) compared to 20.34 kJmol-1 of the blank solution was obtained. The reaction process is spontaneous and endo thermic, as indicated by the ΔH, ΔS and ΔG values calculated. CPE adsorption behaviour fitted best into Freundlich isotherm.
References
Abdelsattar, M., Badawi, A. M., Ibrahim, S., Wasfy, A. F., Tantawy, A. H., Dardir, M. M., "Corrosion Control of Carbon Steel in WaterBased Mud by Nanosized Metallo- Cationic Surfactant Complexes During Drilling Operations", ACS Omega, 5(2020), 30881-30897. https://doi.org/10.1021/acsomega.0c03653
Abdel-Hameed, R., Qureshi, M.T., Abdallah, M., Aljuhani E., Alzharani, A. A., Alfarsi, A., Bakry, A. M., Huwaimel, B. & Farghaly, O., "Recycling of Expired Lactulose Drugs as Eco-Friendly Corrosion Inhibitor for Steel Alloys in Acidic Environment: Gravimetrical and Electrochemical Studies", International Journal of Electrochemical Science, 17 (2022) 221270. https://doi.org/10.20964/2022.12.92
Ade, S.B., Shitole, N.V., & Lonkar S.M., Antifungal drug's used as metal corrosion inhibitor in various acid medium, Int. J. Chem Tech. Res. 6 (7) (2014), 3642–3650.
Aiboudi M., Yousfi, F., Fekkar, G., Bouyazza, L., Ramdani, M., El Azzouzi, M. & Abdel- Rahman, I., Eco-friendly Allium cepa L. seeds extracts as corrosion inhibitor for mild steel in 1 M HCl solutions. J. Mater. Environ. Sci., 10(4) (2019), pp. 339–346.
Ajayi, O., Odusote, J., & Yahya, R., Inhibition of mild steel corrosion using Jatropha Curcas leaf extract. J. Electrochemical Sci Eng., 4(2) (2014), pp. 67–74. https://doi.org/10.5599/jese.2014.0046
Alaoui, K., Dkhireche, N., Touhami, M. E. & El Kacimi, Y., "chapter 5 Review of Application of Imidazole and Imidazole Derivatives as Corrosion Inhibitors of Metals", IGI Global, 2020. https://doi.org/10.4018/978-1-7998-2775-7.ch005
Alrafai, H., Corrosion inhibition properties of the oil extracted from the leaves of Eruca sativa for carbon steel in acidic medium. Int J Electrochem Sci., 17(2022), pp. 1–12. https://doi.org/10.20964/2022.02.24
Ameh, P. O., "Corrosion inhibition and adsorption behaviour for mild steel by Ficus glumosa gum in H2SO4 solution", African Journal of Pure and Applied Chemistry, 6 (7) (2012), 100-106. https://doi.org/10.5897/AJPAC12.001
Ani, J.U., Obi, I.O., Akpomie, K.G., Eze, S.I. & Nwatu, G., Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-Review, Journal of Natural Fibers 19 (7) (2022), 2391–2401, https://doi.org/10.1080/15440478.2020.1818345
Asaad M. A., Ismail, M., Raja, P. B. & Khalid, N. A., Rhizophora Apiculata as Eco-Friendly Inhibitor Against Mild Steel Corrosion in 1M HCl. Surf Rev Lett., 24(8) (2017), pp. 1–11. https://doi.org/10.1142/S0218625X18500130
Aslam, R., Mobin, M., Zehra, S., Obot, I.B. & Ebenso, E.E., Dialkylcystine Gemini and Monomeric -Alkyl Cysteine Surfactants as Corrosion Inhibitors on Mild Steel Corrosion in 1 M HCl Solution: A Comparative Study, ACS Omega, 2(9) (2017), https://doi.org/10.1021/acsomega.7b00501
Atheel, H.A, Dhuha, H.F., Ali, A.A., Abdul Hameed, F. & Yousif, E., Inhibitive effect of atenolol on the corrosion of zinc in hydrochloric acid, Rasayan J. Chem. 10 (3) (2017) 922–928.
Betti, N., Al-Amiery, A., KhalidAl-Azzawi, W. & Isahak, W, N., Corrosion inhibition properties of schif base derivative against mild steel in HCl environment complemented with DFT investigations. Nature Scientifc Reports (2023) 13:8979. https://doi.org/10.1038/s41598-023-36064-w
Dkhireche, N., Galai, M., El Kacimi, Y., Rbaa, M., Ouakki, M., Lakhrissi, B. & EbnTouhami, M., New quinoline derivatives as sulfuric acid inhibitor’s for mild steel. Anal Bioanal Electrochem 10(1) (2018):111–135
Eddy, N.O. & Ameh, P.O., Computational and experimental study on Tapinanthus bangwensis leaves as corrosion inhibitor for mild steel and Al in 0.1 M HCl. Current Topics in Electrochemistry Vol. 23, 2021.
Ech-chihbi, E., Nahlé, A., Salim, R., Oudda H., "An Investigation into Quantum Chemistry and Experimental Evaluation of Imidazopyridine Derivatives as Corrosion Inhibitors for C-Steel in Acidic Media", Journal of Bio- and Tribo-Corrosion, (2019). https://doi.org/10.1007/s40735-019-0217-9
Ekuma, F.K., Ogueji, C. & Okoyeagu, A. Zinc corrosion inhibition by 4-hydroxyl phenyl methylidene-2-(1-phenyl ethylidene) hydrazine carbothioamide (4-HPMHC) and 4-hydroxy phenyl [methylidene] amino-3, 4- dimethyl-5-phenyl cyclo pent-2-en-1- one (4-HPMCP), J. Chem. Soc. Nigeria, 42(2) (2017), 5-10.
Fateh, A., Aliofkhazraei, M. & Rezvanian, A. R., Review of Corrosive Environments for Copper and its Corrosion Inhibitors. Arabian Journal of Chemistry, (2017), doi: http://dx.doi.org/10.1016/j.arabjc. 2017.05.021
Fekkar, G., Yousfi, F., Elmsellem, H., Aiboudi, M., Ramdani, M., Abdеl-Rahman, І., Hammouti, B.., & Bouyazza, L., Eco-friendly chamaerops humilis l. Fruit extract corrosion inhibitor for mild steel in 1 M HCl. International Journal of Corrosion and Scale Inhibition, 9(2) (2020), pp. 446–459. https://doi.org/10.17675/2305-6894-2020-9-2-4
Gu, T., Xu, Z., Zheng, X., Fu, A., Zhang, F., Al-Zaqri, N., Chen, J., Tan, B., & Li, W. (2023). "Lycium barbarum leaf extract as biodegradable corrosion inhibitor for copper in sulfuric acid medium", Industrial Crops and Products. https://doi.org/10.1016/j.indcrop.2023.117181
Guruprasada, A.M., Sachinb, H.P., Swethab, G.A. & Prasannad, B.M., Corrosion inhibition of zinc in 0.1 M hydrochloric acid medium with clotrimazole: Experimental, theoretical and quantum studies. Surfaces and Interfaces, 19 (2020) 100478. https://doi.org/10.1016/j.surfin.2020.100478
Hemapriya, V., Chung, I. M., Parameswari, K., Chitra, S., Kim, S. H., & Prabakaran, M. Corrosion inhibition behavior of benzothiazine derivative on low carbon steel in acid medium: adsorption and quantum chemical investigations, Surf. Rev. Lett. 26 (10) (2019)., 1950066. https://doi.org/10.1142/S0218625X19500665
Hemapriya, V., Prabakaran, M., Chitra, S., Swathika, M., Chung, S. I., "Utilization of biowaste as an eco-friendly 1% biodegradable corrosion inhibitor for mild steel in 1mol/L HCl solution", Arabian Journal of Chemistry, 13 (12) (2020), 8684-8696. https://doi.org/10.1016/j.arabjc.2020.09.060
Hemapriya,V., Chung, I., Kim, S. & Prabakaran, M., Inhibitory effect of biowaste on copper corrosion in 1 M HCl solution, Materials Today Communications, 27(2021), https://doi.org/10.1016/j.mtcomm.2021.102249. https://doi.org/10.1016/j.mtcomm.2021.102249
Hossain N., Islam, M. A. & Chowdhury, M. A., Advances of plant-extracted inhibitors in metal corrosion reduction – Future prospects and challenges. Results in Chemistry, 5 (2023). https://doi.org/10.1016/j.rechem.2023.100883
Ikeuba, A.I. & Okafor, P.C., Green corrosion protection for mild steel in acidic media: saponins and crude extracts of Gongronema latifolium. Pigment & Resin Technology, 48(1) (2019):57-64. https://doi.org/10.1108/PRT-03-2018-0020
Iroha, N. & Maduelosi, N.,‘Corrosion Inhibitive Action and Adsorption Behaviour of Justicia Secunda Leaves Extract as an Eco‐friendly Inhibitor for Aluminium in Acidic Media’, Biointerface Res Appl Chem., 11(5), pp. 13019–13030. https://doi.org/10.33263/BRIAC115.1301913030
Joycee, S., Corrosion mitigation by an eco-friendly inhibitor: Beta vulgaris (beetroot) extract on mild steel in simulated oil well water medium. Int J Corros Scale Inhib., 11(1) (2022), pp. 82–101. https://doi.org/10.17675/2305-6894-2022-11-1-4
Lahbib, H., Hassen, S. B., Gerengi, H., Amor, Y. B.," Inhibition effect of Cynara cardunculus leaf extract on corrosion of St37 steel immersed in seawater with and without bleach solution ", Chemical Engineering Communications, (2020). https://doi.org/10.1080/00986445.2020.1771320
Lai, C., Xie, B., Zou, L., Zheng, X. & Ma, X., Adsorption and Corrosion Inhibition of Mild Steel in Hydrochloric Acid Solution by S-allyl-O,O'-dialkyldithiophosphates, 7(2017). https://doi.org/10.1016/j.rinp.2017.09.012
Loto, C. & Loto, R., Inhibition effect of garlic extracts on the corrosion of alpha brass in nitric acid. Der Pharma Chem., 8(2) (2016); pp. 162–171.
Mahmoud, G. A., Saleh, S., Wanees, A., Mustafa, S. K.,"Dihydropyridine derivatives as controllers for production of hydrogen during zinc dissolution". Chemical Engineering Communications, 206 (6) (2019)., 789-803. https://doi.org/10.1080/00986445.2018.1527319
Mazumder, M. J., Quraishi, M. & Ahmed, A. (2022)."Polymeric Corrosion Inhibitors for Greening the Chemical and Petrochemical Industry", Wiley, 2022. https://doi.org/10.1002/9783527835621
Mobin, M., Ahmad, I., Basik, M., Murmu, M. & Banerjee, P., "Experimental and theoretical assessment of almond gum as an economically and environmentally viable corrosion inhibitor for mild steel in 1M HCl", Sustainable Chemistry and Pharmacy, 18 (2020), 100337. https://doi.org/10.1016/j.scp.2020.100337
Mobin, M., & Rizvi, M., Inhibitory effect of xanthan gum and synergistic surfactant additives for mild steel corrosion in 1M HCl. Carbohydr Polym., 136(2016), pp. 384–393. https://doi.org/10.1016/j.carbpol.2015.09.027
Mzioud, K., Habsaoui, A., Rached, S., Lachhab, R., "Chapter 23 Synergistic Effect from Allium Sativum Essential Oil and Diethylthiourea for Corrosion Inhibition of Carbon Steel in 0.5 MH2SO4 Medium", Springer Science and Business Media LLC, (2022). https://doi.org/10.1007/978-3-031-11397-0_23
Nahlé, A., El Azzouzi, M., Aouniti, A., Abrigach, F., Djedouani, A., Benhiba, F., Touzani, R., Warad, I., Obot, I.B., Zarrouk, A., Hammouti, B., Experimental, Quantum Chemical and Monte Carlo Simulation Studies on the Corrosion Inhibition of Mild Steel by Three New Schiff Base Derivatives. Portugaliae Electrochimica Acta 39(2021), 293-321. https://doi.org/10.4152/pea.2021390501
Njoku, C. N., Enendu, B. N., Okechukwu, S. J., Igboko, N., "Review on anti- corrosion properties of expired antihypertensive drugs as benign corrosion inhibitors for metallic materials in various environments", Results in Engineering, 18 (2023), 101183. https://doi.org/10.1016/j.rineng.2023.101183
Nwigwe, U., The inhibition of Carica papaya leaves extract on the corrosion of cold worked and annealed mild steel in HCl and NaOH solutions using a weight loss technique. Eng Appl Sci Research, 46(2019), pp. 114– 119. https://10.14456/easr.2019.14
Nwigwe, U. S., Nwoye, C. I., Bello, A. S. & Nwankwo, N. E., Azadirachta Indica's adsorptive behavior on mild steel in a sulfuric acid medium. UNIZIK Journal of Engineering and Applied Sciences, 2(2) (2023), 319-331.
Ofuyekpone, O.D., Utub, O.G. & Onyekp, B.O., Corrosion inhibition for alloy 304L (UNS S30403) in H2SO4 1M solution by Centrosema pubescens leaves extract. Applied Surface Science Advances, 3(2021) 100061. https://doi.org/10.1016/j.apsadv.2021.100061
Ogueji, C., Amadi, O. K., Oranuka, D. C., & Onwuka, C. A., Adsorption and inhibitive effect of N- [(4{[(Z)-(4-hydroxy phenyl) methylidene] amino} phenyl) sulfonyl acetamide on the corrosion of mild steel in HCl medium. UMYU Scientifica, 2(4) (2023), 179 – 188. https://doi.org/10.56919/usci.2324.022
Ogueji, C., Mbah, M. C., Amadi, O. K., Okoro, L. N. & Okoli, C. P., Adsorption and thermodynamic study of the inhibition of corrosion of zinc in HCl medium using N- [(4{[(Z)-phenylmethylidene]amino}phenyl)sulfonyl] acetamide. UNIZIK Journal of Engineering and Applied Sciences 3(1) (2024), 416-429.
Ogunleye, O. O., Arinkoola, A. O., Alagbe, S. O., Agbede, O. O., Omodele, A. E., Morakinyo, A. F., Osho, Y. A., "Synthesis of green corrosion inhibitor for mild steel in acidic environment", Indian Chemical Engineer, (2019). https://doi.org/10.1080/00194506.2019.1625815
Okeoma, K.B., Mejeha, I.M. & Akajiaku, S.C., Investigative studies on the inhibitive effects of Newbouldialaevis extracts and magnetic fields on copper corrosion in aqueous acidic media. Research Inventy: International Journal of Engineering And Science,6(2) (2016), 5-14.
Onwu, F.K., Ogueji, C. & Mgbemena, N.M., Inhibition of Corrosion of Zinc in H2SO4 Medium by the Schiff Base, 4-Hydroxy Phenyl Methylidene-2-(l-Phenyl Ethylidene) Hydrazine Carbothioamide (4-HPMHC), DerChemica Sinica, 7(4) (2016), 13-20.
Ouakki, M., Galai, M., Cherkaoui, M., Rif, E. & Hatim, Z., Inorganic compound (Apatite doped by Mg and Na) as a corrosion inhibitor for mild steel in phosphoric acidic medium. Anal Bioanal Electrochem, 10(7) (2018):943–960.
Rathore, A., Sharma, S., Sharma, A., Sharma, S. K. "Evaluation of structure-reactivity correlation of efficient corrosion inhibitor ionic liquids for mild steel in acidic medium", Journal of Dispersion Science and Technology, 2023. https://doi.org/10.1080/01932691.2023.2197996
Rbaa, M., Galai, M., El Kacimi, Y., Ouakki, M., Touir, R., Lakhrissi, B. & EbnTouhami, M., Adsorption properties and inhibition of carbon steel corrosion in a hydrochloric solution by 2-(4,5-diphenyl-4,5-dihydro-1h-imidazol-2-yl)-5 methoxyphenol, Portugaliae. Electrochim Acta, 35(6) (2017):323–338. https://doi.org/10.4152/pea.201706323
Şahin, E. A., "Experimental and theoretical studies of acridine orange as corrosion inhibitor for copper protection in acidic media", Journal of the Indian Chemical Society, 99(3) (2022), 100358. https://doi.org/10.1016/j.jics.2022.100358
Salman, T. et al., Novel ecofriendly corrosion inhibition of mild steel in strong acid environment: Adsorption studies and thermal effects. Int J Corros Scale Inhib., 8(4) (2019), pp. 1123–1137. https://doi.org/10.17675/2305-6894-2019-8-4-19
Shabani-Nooshabadi, M. & Ghandchi, M.S., Santolina chamaecyparissus extract as a natural source inhibitor for 304 stainless steel corrosion in 3.5% NaCl, J. Ind. Eng. Chem. 31(2015), 231–237. https://doi.org/10.1016/j.jiec.2015.06.028
Singh, A., Lin, Y., Ebenso, E. E., Liu, W., Pan, J. & Huang, B., Gingko biloba fruit extract as an eco-friendly corrosion inhibitor for J55 steel in CO2 saturated 3.5% NaCl solution. J Ind Eng Chem., 24(2015), pp. 219–228. https://doi.org/10.1016/j.jiec.2014.09.034
Todres, Z.V. (2019). "Chalcogenadiazoles Chemistry and Applications", CRC Press, 2019
Umoren, S.A., Eduok, U.M., Solomon, M.M., Udoh, A.P.,"Corrosion inhibition by leaves and stem extracts of Sida acuta for mild steel in 1M H2SO4 solutions investigated by chemical and spectroscopic techniques", Arabian Journal of Chemistry, 9 (2016), 5209-5224. https://doi.org/10.1016/j.arabjc.2011.03.008
Wadhwani, P. M, Panchal, V. K, Shah, N. K., "Newly synthesized salicylidene-4,4′-dimorpholine (SDM) assembled on nickel oxide nanoparticles (NiONPs) and its inhibitive effect on mild steel in 2N hydrochloric acid", Applied Surface Science, 2015. https://doi.org/10.1016/j.apsusc.2015.01.105
Wang, J., Cui, L., Chen, B., Chen, X., Lv, Z., Chen, D., Qiang, Y., Xiang, T., "Corrosion inhibition effect of Sycamore leaf extract on copper in H2SO4 solution", Journal of Materials Research and Technology, 26 (2023), 6689-6702. https://doi.org/10.1016/j.jmrt.2023.09.067
Wanees, A. S., Radwan, A. B., Alsharif, M. A. & Abd El Haleem, S. M., Initiation and Inhibition of Pitting Corrosion on Reinforcing Steel under Natural Corrosion Conditions. Mater. Chem. Phys. 2017, 190, 79–95. https://doi.org/10.1016/j.matchemphys.2016.12.048
Wanees, S.A., & Seda, S. H., Corrosion inhibition of zinc in aqueous acidic media using a novel synthesized Schiff base – an experimental and theoretical study. Journal of Dispersion Science and Technology, (2019). https://doi.org/10.1080/01932691.2018.1544080
Yadav, S., Kaushik, S., Dheer, N., Kumar, S., SIngh, G., Chaudhary, M., Gupta, M., (2023). "Experimental investigation of anti-corrosive behaviour of Beta vulgaris: A green approach", Journal of Applied and Natural Science, 2023. https://doi.org/10.1016/j.matpr.2023.07.210
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